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Ice crystals physically damage peptide structures

This work fixes a previously obscure piece of the puzzle regarding glutathiones role in ER biology and offers tantalizing prospects for disease intervention through metabolic and molecular engineering

Chain elongation of the intermediate is mediated by a condensation (C) domain catalyzing the nucleophilic attack of the downstream PCP-bound acceptor monomer on the activated thioester of the upstream PCP-bound donor monomer 13 , thus giving rise to the dipeptide intermediate D- O -Leu-D-Ala- S -PCP

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